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In order to connect to the Motorola Xoom to a Windows PC to transfer media, documents and other files to your tablet, you must first download and install the Motorola Xoom USB driver, available here - http://ukblog.im-mobility.com/public/support/Motorola/XOOM/
Simply run the installer and then reboot your PC. Once rebooted, upon connection the Xoom will be recognised as a removable storage device in My Computer, enabling you to copy and paste or drag and drop files to and from it to your desktop.